Create a Outlook Profile

Create an Outlook profileWindows

In Outlook, select File > Account Settings > Manage Profiles

Choose Show Profiles > Add.

In the Profile Name box, type a name for the profile, and then choose OK.

Type in your new email address and password. Accept all other options

Set profile as default

MAC

From Finder, open the Applications folder.

Ctrl+click or right-click Microsoft Outlook, and then select Show Package Contents.

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Open Contents > SharedSupport, and then launch Outlook Profile Manager.

Type in your new email address and Password.

Other options if you want to remove the old profile or make this one the new default.